High-performance tin-oxide supercapacitors using hydrazine functionalising assisted by hydrogen plasma treatment

Hassan Abdollahi; Mahmoud Samkan; Mohammad Ala Mohajerzadeh; Zeinab Sanaee; Shams Mohajerzadeh

High-performance tin-oxide supercapacitors using hydrazine functionalising assisted by hydrogen plasma treatment

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Author(s): Hassan Abdollahi¹ ; Mahmoud Samkan¹ ; Mohammad Ala Mohajerzadeh^{2, 3} ; Zeinab Sanaee^{2, 3} ; Shams Mohajerzadeh²
- Affiliations: 1: Department of Electrical Engineering, Shahid Sattari Aeronautical University of Science and Technology , Tehran , Iran ;
  2: Thin Film and Nanoelectronic Lab , School of Electrical and Computer Engineering, University of Tehran , Tehran , Iran ;
  3: Nano-fabricated Energy Devices Lab , School of Electrical and Computer Engineering, University of Tehran , Tehran , Iran
Source: Volume 14, Issue 12, 23 October 2019, p. 1268 – 1273
DOI: 10.1049/mnl.2019.0214 , Online ISSN 1750-0443

Received 05/04/2019, Accepted 15/08/2019, Revised 28/07/2019, Published 23/10/2019

For the first time, the effects of adding hydrazine solution to tin-oxide sol–gel to be used as an electrode in high-performance supercapacitors have been studied. The mixed solution has been spin-coated on stainless steel foils as substrates followed by exposing to hydrogen plasma treatment. The results show the effectiveness of adding hydrazine to tin-oxide sol–gel, compared to pure tin-oxide sol–gel. The electrochemical tests such as cyclic-voltammetry and charge–discharge characteristics have been conducted, and the findings demonstrate the favourable contribution of adding hydrazine in increasing the capacitance of the supercapacitor. The physical properties of the tin-oxide material have been analysed by means of FESEM, XRD, TEM, FT-IR spectroscopy and Raman spectroscopy to have a better understanding of preparation procedure and better insight in material synthesis. The electrochemical tests demonstrate a high capacitance of 18 mF/cm² for the sample treated with hydrazine during the sol–gel processing which is around 40% higher than the merely prepared tin-oxide sample. The measured values for the capacitance versus rate show a rather linear correlation between these parameters, further corroborating an electric-double layer-based performance for such devices.

References

1. 1)
  - 27. Wang, C., Hu, Y., Qian, Y., et al: ‘A novel method to prepare nanocrystalline SnO2’, J. Nano Structured Mater., 1996, 7, p. 421 (doi: 10.1016/0965-9773(96)00016-5).
2. 2)
  - 21. Liu, C.G., Yu, Z.N., Neff, D., et al: ‘Graphene-based supercapacitor with an ultrahigh energy density’, Nano Lett., 2010, 10, pp. 4863–4868 (doi: 10.1021/nl102661q).
3. 3)
  - 18. Johari, A., Bhatnagar, M. C., Rana, V.: ‘Growth, characterization and I-V characteristics of tin oxide (SnO2) nanowires’, J. Adv. Mater. Lett., 2012, 3, p. 515 (doi: 10.5185/amlett.2012.icnano.251).
4. 4)
  - 5. Bae, J., Park, Y.J., Yang, J.C., et al: ‘Towards wearable and stretchable fabric-based supercapacitors: novel ZnO and SnO2 nanowires – carbon fiber and carbon paper hybrid structure’, J. Solid State Electrochem., 2015, 19, p. 211 (doi: 10.1007/s10008-014-2544-6).
5. 5)
  - 21. Diéguez, A., Romano-Rodríguez, A., Vilà J, A., et al: ‘The complete Raman spectrum of nanometric SnO2 particles’, J. Appl. Phys., 2001, 90, p. 1550 (doi: 10.1063/1.1385573).
6. 6)
  - 23. Cabot, A., Arbiol, J., Rossinyol Morante, E., et al: ‘Synthesis of tin oxide nanostructures with controlled particle size using mesoporous frameworks’, J. Electrochem. Solid-State Lett., 2004, 7, p. 93 (doi: 10.1149/1.1664054).
7. 7)
  - 22. Jang, D.M., Jung, H., Hoa, N.D., et al: ‘Tin oxide-carbon nanotube composite for NOX sensing’, J. Nanosci. Nanotechnol., 2012, 12, p. 1425 (doi: 10.1166/jnn.2012.4656).
8. 8)
  - 10. Li, R., Ren, X., Zhang, F., et al: ‘Synthesis of Fe3O4@SnO2 core–shell nanorod film and its application as a thin-film supercapacitor electrode’, J. Chem. Commun., 2012, 48, p. 5010 (doi: 10.1039/c2cc31786a).
9. 9)
  - 13. Li, F., Song, J., Yang, H., et al: ‘One-step synthesis of graphene/SnO2 nanocomposites and its application in electrochemical supercapacitors’, J. Nanotechnol., 2009, 20, p. 455602 (doi: 10.1088/0957-4484/20/45/455602).
10. 10)
  - 19. Sun, S.H., Meng, G.W., Zhang, G.X., et al: ‘Raman scattering study of rutile SnO2 nanobelts synthesized by thermal evaporation of Sn powders’, J. Chem. Phys. Lett., 2003, 376, p. 103 (doi: 10.1016/S0009-2614(03)00965-5).
11. 11)
  - 17. Iqbal, M.Z., Wang, F., Din, R.U., et al: ‘Synthesis of novel clinopinacoid structure of stannous oxide and hydrogen absorption characteristics’, J. Mater. Lett., 2012, 78, p. 50 (doi: 10.1016/j.matlet.2012.03.056).
12. 12)
  - 20. Xie, Y., Zhu, F.: ‘Electrochemical capacitance performance of polyaniline/tin oxide nanorod array for supercapacitor’, J. Solid State Electrochem., 2017, 21, p. 1675 (doi: 10.1007/s10008-017-3525-3).
13. 13)
  - 25. Marikkannan, M., Vishnukanthan, V., Vijayshankar, A., et al: ‘A novel synthesis of tin oxide thin films by the sol-gel process for optoelectronic applications’, J. AIP Adv., 2015, 5, p. 027122 (doi: 10.1063/1.4909542).
14. 14)
  - 26. Sinha, A.K., Manna, P.K., Pradhan, M., et al: ‘Tin oxide with a p–n heterojunction ensures both UV and visible light photo catalytic activity’, J. R. Soc. Chem., 2014, 4, p. 208.
15. 15)
  - 9. Kwon, O., Deka, B.K., Kim, J., et al: ‘Electrochemical performance evaluation of tin oxide nanorod-embedded woven carbon fiber composite supercapacitor’, J. Energy Res., 2018, 42, (2), pp. 490–498 (doi: 10.1002/er.3827).
16. 16)
  - 14. Wang, W., Hao, Q., Lei, W., et al: ‘Graphene/SnO2/polypyrrole ternary nanocomposites as supercapacitor electrode materials’, J. RSC Adv., 2012, 2, p. 10268 (doi: 10.1039/c2ra21292g).
17. 17)
  - 2. Hwang, S.W., Hyun, S.H.: ‘Synthesis and characterization of tin oxide/carbon aerogel composite electrodes for electrochemical supercapacitors’, J. Power Sources, 2007, 172, p. 451 (doi: 10.1016/j.jpowsour.2007.07.061).
18. 18)
  - 15. Oehl, N., Schmuelling, G., Knipper, M., et al: ‘In situ X-ray diffraction study on the formation of α-Sn in nanocrystalline Sn-based electrodes for lithium-ion batteries’, J. CrystEngComm., 2015, 17, p. 8500 (doi: 10.1039/C5CE01841B).
19. 19)
  - 4. Li, Z., Chang, T., Yun, G., et al: ‘2D tin dioxide nanoplatelets decorated graphene with enhanced performance supercapacitor’, J. Alloys Compd., 2014, 586, p. 353 (doi: 10.1016/j.jallcom.2013.10.037).
20. 20)
  - 24. Tan, L., Wang, L., Wang, Y.: ‘Hydrothermal synthesis of SnO2 nanostructures with different morphologies and their optical properties’, J. Nanomater., 2011, 1, p. 529874.
21. 21)
  - 7. Velmurugana, V., Srinivasaraoa, U., Ramachandrana, R., et al: ‘Synthesis of tin oxide/graphene (snO2/G) nanocomposite and its electrochemical properties for supercapacitor applications’, J. Mater. Res. Bull., 2016, 84, p. 145 (doi: 10.1016/j.materresbull.2016.07.015).
22. 22)
  - 6. Lima, S.P., Huanga, N.M., Lim, H.N.: ‘Solvothermal synthesisofSnO2/graphene nanocomposites for supercapacitor application’, J. Ceramics Int., 2003, 39, p. 6647 (doi: 10.1016/j.ceramint.2013.01.102).
23. 23)
  - 1. Kuok, F.H., Liao, C.Y., Chen, C.W., et al: ‘Screen-printed SnO2/CNT quasi-solid-state gel-electrolyte supercapacitor’, J. Mater. Res. Express, 2017, 4, (7), 115501.
24. 24)
  - 3. Yan, J., Khoo, E., Sumboja, A., et al: ‘Facile coating of manganese oxide on tin oxide nanowires with high-performance capacitive behavior’, J. ACS Nano, 2010, 4, (7), p. 4247 (doi: 10.1021/nn100592d).
25. 25)
  - 8. Kuo, S.L., Wu, N.L.: ‘Composite supercapacitor containing tin oxide and electroplated ruthenium oxide’, J. Electrochem. Solid State Lett., 2003, 6, p. 85 (doi: 10.1149/1.1563872).
26. 26)
  - 12. Selvan, R.K., Perelshtein, I., Perkas, N., et al: ‘Synthesis of hexagonal-shaped SnO2 nanocrystals and SnO2@C nanocomposites for electrochemical redox supercapacitors’, J. Phys. Chem., 2008, 112, p. 1825.
27. 27)
  - 16. Han, Z., Guo, N., Li, F., et al: ‘Solvothermal preparation and morphological evolution of stannous oxide powders’, J. Mater. Lett., 2001, 48, p. 99 (doi: 10.1016/S0167-577X(00)00286-X).

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High-performance tin-oxide supercapacitors using hydrazine functionalising assisted by hydrogen plasma treatment

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