access icon free CTAB assisted co-precipitation synthesis of NiO nanoparticles and their efficient potential towards the removal of industrial dyes

In this work, nickel oxide nanoparticles (NiO NPs) have been synthesised via cost-effective and highly convenient co-precipitation method, using cetyl trimethyl ammonium bromide (CTAB) as capping agent and NaOH as a reducing agent. The as-synthesised NPs have been analysed by a number of spectroscopic and microscopic techniques such as UV–visible spectroscopy, transmission electron microscope, X-ray diffraction, Fourier transformed infrared and energy dispersive X-ray. The prepared NiO NPs hold the prodigious potential towards the photocatalytic degradation of reactive blue 81 and Coomassie brilliant blue R-250 dyes with degradation efficiency of 90.8 and 95.7% and have high dye degradation rate constants of 1.3 × 10 2 min 1 and 2.2 × 10 2 min 1, respectively. Thus, this work signifies an efficient way to employ the NiO NPs as effective photocatalyst towards the alleviation of noxious industrial dyes.

Inspec keywords: Fourier transform infrared spectra; precipitation (physical chemistry); photodissociation; nanoparticles; reaction rate constants; semiconductor growth; nanofabrication; photocatalysis; X-ray chemical analysis; transmission electron microscopy; nickel compounds; wide band gap semiconductors; scanning electron microscopy; ultraviolet spectra; X-ray diffraction; photocatalysts; dyes; visible spectra

Other keywords: photocatalytic degradation; X-ray diffraction; cetyl trimethyl ammonium bromide; UV-visible spectroscopy; reactive blue 81; NiO nanoparticles; reducing agent; noxious industrial dyes; Fourier transformed infrared spectroscopy; NiO; highly convenient coprecipitation method; nickel oxide nanoparticles; efficient potential; energy dispersive X-ray; industrial dye removal; degradation efficiency; CTAB assisted coprecipitation synthesis; transmission electron microscopy; high dye degradation rate constants; effective photocatalyst; Coomassie brilliant blue R-250 dyes; capping agent

Subjects: Optical properties of other inorganic semiconductors and insulators (thin films, low-dimensional and nanoscale structures); Low-dimensional structures: growth, structure and nonelectronic properties; Visible and ultraviolet spectra of other nonmetals; Other methods of nanofabrication; Electromagnetic radiation spectrometry (chemical analysis); Structure of solid clusters, nanoparticles, nanotubes and nanostructured materials; Measurements of chemical rate constants, reaction cross sections, and activation energies; Heterogeneous catalysis at surfaces and other surface reactions; Infrared and Raman spectra in inorganic crystals; Oxide and ferrite semiconductors; Photolysis and photodissociation by IR, UV and visible radiation; Nanometre-scale semiconductor fabrication technology

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http://iet.metastore.ingenta.com/content/journals/10.1049/mnl.2018.5489
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