Synthesis and photocatalytic activity of YVO4 nanocrystals through ethylenediaminetetraacetate-assisted hydrothermal process
- Author(s): Li Li 1 ; Mai Xu 1 ; Airong Xu 1 ; Yue Wang 1 ; Lu Pan 1 ; Zhimei Sun 1 ; Fengwu Wang 1
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View affiliations
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Affiliations:
1:
School of Chemistry and Materials Engineering, Huainan Normal University , Huainan 232038 , People's Republic of China
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Affiliations:
1:
School of Chemistry and Materials Engineering, Huainan Normal University , Huainan 232038 , People's Republic of China
- Source:
Volume 14, Issue 7,
26
June
2019,
p.
711 – 716
DOI: 10.1049/mnl.2018.5127 , Online ISSN 1750-0443
Tetragonal YVO4 nanoparticles of different sizes were successfully prepared through an ethylenediaminetetraacetate -mediated hydrothermal method. The crystalline structure and optical property were characterised by transmission electron microscopy (TEM), high resolution TEM, X-ray diffraction, photoluminescence spectra, and ultraviolet–visible diffuse reflection spectra, respectively. The as-prepared YVO4 displayed excellent photocatalytic performance. Among them, sample S2 has the highest photocatalytic activity with a photodegradation efficiency of 85% within 180 min illumination, which is due to its smaller size and larger specific surface area. The investigation on the photocatalytic mechanism reveals that hydroxyl radical (•OH) is the main active species in the photocatalytic oxidation process.
Inspec keywords: photoluminescence; nanoparticles; photocatalysts; surface morphology; oxidation; visible spectra; X-ray diffraction; crystal growth from solution; ultraviolet spectra; nanofabrication; transmission electron microscopy; yttrium compounds; photocatalysis
Other keywords: ultraviolet–visible diffuse reflection spectra; ethylenediaminetetraacetate-assisted hydrothermal process; X-ray diffraction; photoluminescence spectra; transmission electron microscopy; photocatalytic activity; ethylenediaminetetraacetate-mediated hydrothermal method; photocatalytic mechanism; photocatalytic oxidation process; photodegradation efficiency; tetragonal YVO4 nanoparticles; hydroxyl radical; YVO4; crystalline structure; high resolution TEM; specific surface area
Subjects: Solid surface structure; Crystal growth from solution; Structure of solid clusters, nanoparticles, nanotubes and nanostructured materials; Visible and ultraviolet spectra of other nonmetals; Nanofabrication using crystal growth techniques; Photoluminescence in other inorganic materials; Photolysis and photodissociation by IR, UV and visible radiation; Heterogeneous catalysis at surfaces and other surface reactions
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