Surfactant-enhanced spectrofluorimetric detection after magnetic nanoparticles-based micro-solid-phase extraction coupled with dispersive liquid–liquid micro-extraction for determination of ciprofloxacin in human plasma

Hossein Rastegar; Manouchehr Dadgarnejad; Fatemeh Zolfaghari; Zohreh Taherimaslak; Mitra Amoli-Diva

Surfactant-enhanced spectrofluorimetric detection after magnetic nanoparticles-based micro-solid-phase extraction coupled with dispersive liquid–liquid micro-extraction for determination of ciprofloxacin in human plasma

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Author(s): Hossein Rastegar¹ ; Manouchehr Dadgarnejad¹ ; Fatemeh Zolfaghari¹ ; Zohreh Taherimaslak¹ ; Mitra Amoli-Diva²
- Affiliations: 1: Cosmetic Products Research Center , Food and Drug Research Institute, Food and Drug Administration, MOHE , Tehran , Iran ;
  2: Faculty of Chemistry , Kharazmi (Tarbiat Moalem) University , Tehran , Iran
Source: Volume 13, Issue 11, November 2018, p. 1564 – 1569
DOI: 10.1049/mnl.2018.5101 , Online ISSN 1750-0443

Received 18/12/2017, Accepted 10/07/2018, Revised 07/06/2018, Published 01/11/2018

A sensitive and fast micro-solid-phase extraction (μ-SPE) coupled with dispersive liquid–liquid micro-extraction (DLLME) was reported before micelle enhanced spectrofluorimetric detection for determination of ciprofloxacin antibiotic in human plasma samples. The DLLME was performed using methanol as disperser and 1-octanol as extracting solvent. Oleic acid-modified Fe₃O₄ nanoparticles (as hydrophobic adsorbents) were applied in μ-SPE step to extract the analyte from DLLME procedure. The method uses the advantageous of high surface area and strong superparamagnetism of these nanoparticles to many avoid labourhood column/cartridge-passing processes of traditional SPE. The major parameters affecting signal enhancement and analyte recovery were evaluated and optimised. Under the optimal conditions, the calibration curve (with calibration equation of I _f = 2.5826 C + 10.273) was linear in the range 0.5–600 μg L⁻¹ (R ² = 0.997) with low limit of detection of 0.21 µg L⁻¹ and limit of quantification of 0.63 µg L⁻¹. The intra-day and inter-day precisions (as relative standard deviation) were in the range of 1.01–1.67% and high recoveries in the range of 93.5–102.4% were obtained. The results demonstrated that the proposed method is easy, low cost, and accurate. In addition, it confirms that choosing extraction solvent was not restricted to the high-density solvents which can extent the versatility of DLLME.

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Surfactant-enhanced spectrofluorimetric detection after magnetic nanoparticles-based micro-solid-phase extraction coupled with dispersive liquid–liquid micro-extraction for determination of ciprofloxacin in human plasma

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