Enhancement of photocatalytic activity for fold-like ZnO via hybridisation with graphene
- Author(s): Xia Kong 1 ; Yawei Hu 1 ; Wei Pan 2
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View affiliations
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Affiliations:
1:
College of Chemistry and Chemical Engineering , Shaanxi University of Science and Technology , Xi'an, Shaanxi 710021 , People's Republic of China ;
2: State Key Laboratory of New Ceramics and Fine Processing , Tsinghua University , Beijing 100084 , People's Republic of China
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Affiliations:
1:
College of Chemistry and Chemical Engineering , Shaanxi University of Science and Technology , Xi'an, Shaanxi 710021 , People's Republic of China ;
- Source:
Volume 13, Issue 2,
February
2018,
p.
232 – 236
DOI: 10.1049/mnl.2017.0395 , Online ISSN 1750-0443
Fold-like ZnO nanoparticles were prepared by hydrothermal method, and followed by hybridisation with graphene to form graphene/ZnO composite. Photocatalytic properties of prepared samples were investigated by degrading methylene blue solution. It was found that the photocatalytic activity of ZnO has been much enhanced by hybridisation with graphene under either ultraviolet or visible irradiation. After four recycles of photocatalytic experiments, graphene/ZnO photocatalyst has not exhibited any great loss in photocatalytic activity. According to the photo-electrochemical experimental results, the possible mechanism of the enhanced photocatalytic activity could be attributed to the increased adsorption ability, the effective separation of electron–hole pairs and the excellent electron transport characteristics of graphene. Thus, this new and highly effective graphene/ZnO composite could be a perfect candidate in the field of photocatalysis, which provides a new idea for the construction of other photocatalysts based on graphene and semiconductor.
Inspec keywords: catalysis; adsorption; II-VI semiconductors; nanoparticles; graphene; photochemistry; zinc compounds; wide band gap semiconductors; nanofabrication
Other keywords: electron–hole pair separation; methylene blue solution; adsorption ability; hydrothermal method; photo-electrochemical experimental results; hybridisation; ultraviolet irradiation; graphene; visible irradiation; electron transport characteristics; C-ZnO; fold-like nanoparticles; photocatalytic activity
Subjects: Methods of nanofabrication and processing; Photolysis and photodissociation by IR, UV and visible radiation; Adsorption and desorption kinetics; evaporation and condensation; Low-dimensional structures: growth, structure and nonelectronic properties; Heterogeneous catalysis at surfaces and other surface reactions
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