© The Institution of Engineering and Technology
A new generalised model of the electrowetting of microfluids has been proposed. Instead of the conventional Young–Lippmann formula, dynamic minimising of the total energy of system which is superposition of capillary free energy and electric energy has been utilised to calculate the contact angle as indicator of wetting behaviour. The change of interfacial energy of liquid/solid interface and change in relative permittivity of solution in the presence of colloid particles have also been considered in the developed model. The model predicts that contact angle saturation decreases in the presence of colloid particles both in DC and AC conditions. The model also predicts that the reduction of contact angle by applying potential is higher in the case of TiO2/water microfluidic system which is in agreement with experimental data reported in literature.
References
-
-
1)
-
10. Hong, J.S., Ko, S.H., Kang, K.H., et al: ‘A numerical investigation on Ac electrowetting of a droplet’, Microfluidics Nanofluidics, 2008, 5, (2), pp. 263–271 (doi: 10.1007/s10404-007-0246-4).
-
2)
-
2. Orejon, D., Sefiane, K., Shanahan, M.E.R.: ‘Young–Lippmann equation revisited for nano-suspensions’, Appl. Phys. Lett., 2013, 102, (20), p. 201601 (doi: 10.1063/1.4807120).
-
3)
-
12. Gharagozlou, M., Ganjkhanlou, Y.: ‘Effect of Fe addition on phase transformation of titanium dioxide nanocrystals prepared by pechini-type sol–gel method’, IET Micro Nano Lett., 2012, 7, (8), pp. 872–875 (doi: 10.1049/mnl.2012.0469).
-
4)
-
8. Klarman, D., Andelman, D., Urbakh, M.: ‘A model of electrowetting, reversed electrowetting, and contact angle saturation’, Langmuir, 2011, 27, (10), pp. 6031–6041 (doi: 10.1021/la2004326).
-
5)
-
4. Krupenkin, T., Taylor, J.A.: ‘Reverse electrowetting as a new approach to high-power energy harvesting’, Nat. Commun., 2011, 2, p. 448 (doi: 10.1038/ncomms1454).
-
6)
-
5. Lippmann, G.: ‘Relations entre Les Phénomènes Électriques Et Capillaires’, Ann. Chim. Phys., 1875, 5, pp. 494–549.
-
7)
-
18. Saeki, F., Baum, J., Moon, H., et al: ‘Electrowetting on dielectrics (Ewod): reducing voltage requirements for microfluidics, polym’, Mater. Sci. Eng., 2001, 85, pp. 12–13.
-
8)
-
15. Sun, T., Bernabini, C., Morgan, H.: ‘Single-colloidal particle impedance spectroscopy: complete equivalent circuit analysis of polyelectrolyte microcapsules’, Langmuir, 2010, 26, (6), pp. 3821–3828 (doi: 10.1021/la903609u).
-
9)
-
9. Eral, H.B., Augustine, D.M., Duits, M.H.G., et al: ‘Suppressing the coffee stain effect: how to control colloidal self-assembly in evaporating drops using electrowetting’, Soft Matter, 2011, 7, (10), pp. 4954–4958 (doi: 10.1039/c1sm05183k).
-
10)
-
3. Duduś, A., Blue, R., Konstantaki, M., et al: ‘Optical characterisation of long-period grating using liquid droplets on an electrowetting-on-dielectric platform’, Micro Nano Lett., 2014, 9, (6), pp. 399–402 (doi: 10.1049/mnl.2014.0188).
-
11)
-
11. Oh, J.M., Ko, S.H., Kang, K.H.: ‘Shape oscillation of a drop in Ac electrowetting’, Langmuir, 2008, 24, (15), pp. 8379–8386 (doi: 10.1021/la8007359).
-
12)
-
23. Young, T.: ‘An essay on the cohesion of fluids’, Phil. Trans. R. Soc. Lond., 1805, 95, pp. 65–87 (doi: 10.1098/rstl.1805.0005).
-
13)
-
14. Harris, J.W., Stocker, H.: ‘Spherical segment (spherical cap)’, in ‘Handbook of mathematics and computational science’ (Springer-Verlag, 1998).
-
14)
-
16. Lin, J., Masaaki, N., Tsukune, A., et al: ‘Ta2O5 thin films with exceptionally high dielectric constant’, Appl. Phys. Lett., 1999, 74, (16), pp. 2370–2372 (doi: 10.1063/1.123854).
-
15)
-
7. Peykov, V., Quinn, A., Ralston, J.: ‘Electrowetting: a model for contact-angle saturation’, Colloid Polym. Sci., 2000, 278, (8), pp. 789–793 (doi: 10.1007/s003960000333).
-
16)
-
6. Chamakos, N.T., Kavousanakis, M.E., Papathanasiou, A.G.: ‘Neither Lippmann nor Young: enabling electrowetting modeling on structured dielectric surfaces’, Langmuir, 2014, 30, (16), pp. 4662–4670 (doi: 10.1021/la500408j).
-
17)
-
1. Frieder, M., Jean-Christophe, B.: ‘Electrowetting: from basics to applications’, J. Phys., Condens. Matter, 2005, 17, (28), p. R705 (doi: 10.1088/0953-8984/17/28/R01).
-
18)
-
17. Dash, R.K., Borca-Tasciuc, T., Purkayastha, A., et al: ‘Electrowetting on dielectric-actuation of microdroplets of aqueous bismuth telluride nanoparticle suspensions’, Nanotechnology, 2007, 18, p. 475711 (doi: 10.1088/0957-4484/18/47/475711).
http://iet.metastore.ingenta.com/content/journals/10.1049/mnl.2016.0327
Related content
content/journals/10.1049/mnl.2016.0327
pub_keyword,iet_inspecKeyword,pub_concept
6
6