Highly compression-tolerant folded carbon nanotube/paper as solid-state supercapacitor electrode
An original highly compression-tolerant folded carbon nanotube (CNT)/paper electrode, which could be assembled into compressible solid-state supercapacitor with polyvinyl alcohol/phosphoric acid gel electrolyte, is designed. It is worth mentioning that both the compression-tolerant ability of the folded structure and the strain ability of the CNT electrode are conducive to achieving the compressible supercapacitor. Such device could withstand pressure and shape-changing, which has great potential to be used in various environments. This compressible solid-state supercapacitor also owns the maximum specific capacitance of 11.07 mF/cm2, and capacitance retention retains more than 90% after 100 cycling times. Furthermore, the stability performance of the device is also discussed which is almost steady under 50% strain state. When two devices are connected in serial and fully charged, this power unit could light up a red light emitting diode continuously even under the compression state. Therefore, this device performs as a promising candidate to be compatible with other compression-tolerant electronics and enlightens a broad field of compressible energy storage and self-powered systems.