Hydrothermal synthesis and controlled growth of tungsten disulphide nanostructures from one-dimension to three-dimensions

Shixiu Cao; Tianmo Liu; Wen Zeng; Shahid Hussain; Xianghe Peng

Hydrothermal synthesis and controlled growth of tungsten disulphide nanostructures from one-dimension to three-dimensions

View Fulltext

Author(s): Shixiu Cao ^{1, 2} ; Tianmo Liu ^{1, 3} ; Wen Zeng ¹ ; Shahid Hussain ¹ ; Xianghe Peng ⁴
- Affiliations: 1: College of Materials Science and Engineering, Chongqing University, Chongqing 400044, People's Republic of China;
  2: Chongqing Key Laboratory of Micro/Nano Materials Engineering and Technology, Research Center for Material Interdisciplinary Science, Chongqing University of Arts and Science, Chongqing 402160, People's Republic of China;
  3: National Engineering Research Center for Mg Alloys, Chongqing University, Chongqing 400044, People's Republic of China;
  4: Chongqing Key Laboratory of Heterogeneous Material Mechanics, Chongqing University, Chongqing 400044, People's Republic of China
Source: Volume 10, Issue 3, March 2015, p. 183 – 186
DOI: 10.1049/mnl.2014.0516 , Online ISSN 1750-0443

Received 01/09/2014, Accepted 27/11/2014, Revised 03/11/2014, Published 24/02/2015

Three kinds of tungsten disulphide (WS₂) such as nanospheres, nanowires and nanobelts have been synthesised using cetyltrimethyl ammonium bromide (CTAB) as a surfactant. The structural features of the as-prepared WS₂ were characterised by X-ray powder diffraction and scanning electron microscopy. The CTAB surfactants played a critical role in producing different WS₂ nanostructures. The growth mechanism of WS₂ nanostructures is proposed in detail and the schematic representation of the formation mechanism is also shown. Also, the optical absorption property of the WS₂ nanostructures was investigated. This reported work may be helpful to investigate structurally other metal chalcogenide materials with different morphologies.

References

1. 1)
  - 34. Zeng, W.: ‘Facile synthesis of highly VOCs-response alpha-MoO3 nanosheets using hydrothermal process’, Nanosci. Nanotechnol. Lett., 2013, 5, pp. 986–989 (doi: 10.1166/nnl.2013.1656).
2. 2)
  - 10. Murugesan, S.: ‘Room temperature electrodeposition of molybdenum sulfide for catalytic and photoluminescence applications’, ACS Nano, 2013, 7, pp. 8199–8205 (doi: 10.1021/nn4036624).
3. 3)
  - 31. Carmalt, C.J.: ‘Atmospheric pressure chemical vapour deposition of WS2 thin films on glass’, Polyhedron, 2003, 22, pp. 1499–1505 (doi: 10.1016/S0277-5387(03)00194-3).
4. 4)
  - 40. Ge, J.P.: ‘Formation of disperse nanoparticles at the oil/water interface in normal microemulsions’, Chem., Eur. J., 2006, 12, pp. 6552–6558 (doi: 10.1002/chem.200600454).
5. 5)
  - 7. Wu, M.Y.: ‘Hydrothermal synthesis of novel SnO2 nanoflowers and their gas-sensing properties’, Mater. Lett., 2013, 104, pp. 34–36 (doi: 10.1016/j.matlet.2013.04.010).
6. 6)
  - 1. Therese, H.A.: ‘Facile large scale synthesis of WS2 nanotubes from WO3 nanorods prepared by a hydrothermal route’, Solid State Sci., 2005, 7, pp. 67–72 (doi: 10.1016/j.solidstatesciences.2004.10.006).
7. 7)
  - D.D. Liang , S.S. Tang , J.B. Liu , J.H. Liu , X.L. Lv , L.J. Kang . Large scale hydrothermal synthesis of PbS nanorods. Mater. Lett. , 2426 - 2429
8. 8)
  - 9. Lukowski, M.A.: ‘Enhanced hydrogen evolution catalysis from chemically exfoliated metallic MoS2 nanosheets’, J. Am. Chem. Soc., 2013, 135, pp. 10274–10277 (doi: 10.1021/ja404523s).
9. 9)
  - 27. Zhu, L.N.: ‘Tribological properties of WS2 composite film prepared by a two-step method’, Vacuum, 2010, 85, pp. 16–21 (doi: 10.1016/j.vacuum.2010.03.003).
10. 10)
  - 30. Chung, J.W.: ‘WS2 thin films by metal organic chemical vapor deposition’, J. Cryst. Growth, 1998, 186, pp. 137–150 (doi: 10.1016/S0022-0248(97)00479-X).
11. 11)
  - 32. Ma, L.: ‘One-pot hydrothermal synthesis of MoS2 nanosheets/C hybrid microspheres’, Ceram. Int., 2012, 38, pp. 229–234 (doi: 10.1016/j.ceramint.2011.06.056).
12. 12)
  - 35. Miao, B.: ‘Syntheses and mechanism of WO3 center dot H2O nanoflowers assembled of square nanoplates with the assistance of oxalic acid’, Nanosci. Nanotechnol. Lett., 2013, 7, pp. 765–769 (doi: 10.1166/nnl.2013.1609).
13. 13)
  - 3. Tenne, R.: ‘Polyhedral and cylindrical structures of tungsten disulphide’, Nature, 1992, 360, pp. 444–446 (doi: 10.1038/360444a0).
14. 14)
  - 4. Sun, S.B.: ‘Synthesis and structural characterization of tungsten disulfide nanomaterials’, Mater. Lett., 2011, 65, pp. 3164–3166 (doi: 10.1016/j.matlet.2011.06.118).
15. 15)
  - 12. Brown, S.: ‘Bulk vs nanoscale WS2: finite size effects and solid-state lubrication’, Nano Lett., 2007, 7, pp. 2365–2369 (doi: 10.1021/nl0710147).
16. 16)
  - 6. Pol, V.G.: ‘Micro to nano conversion: a one-step, environmentally friendly, solid state, bulk fabrication of WS2 and MoS2 nanoplates’, Cryst. Growth Des., 2008, 8, pp. 1126–1132 (doi: 10.1021/cg0700972).
17. 17)
  - 15. Maharaj, D.: ‘Effect of MoS2 and WS2 nanotubes on nanofriction and wear reduction in dry and liquid environments’, Tribol. Lett., 2013, 49, pp. 323–339 (doi: 10.1007/s11249-012-0071-0).
18. 18)
  - 33. Tang, G.G.: ‘Surfactant-assisted hydrothermal synthesis and characterization of WS2 nanorods’, Mater. Lett., 2011, 65, pp. 3457–3460 (doi: 10.1016/j.matlet.2011.07.033).
19. 19)
  - 21. Gao, B., Fan, H., Zhang, X.: ‘Hydrothermal synthesis of single crystal MoO3 nanobelts and their electrochemical properties as cathode electrode materials for rechargeable lithium batteries’, J. Phys. Chem. Solids, 2012, 73, (3), pp. 423–429 (doi: 10.1016/j.jpcs.2011.11.019).
20. 20)
  - 41. Niederberger, M.: ‘Oriented attachment and mesocrystals: non-classical crystallization mechanisms based on nanoparticle assembly’, Phys. Chem. Chem. Phys., 2006, 8, pp. 3271–3287 (doi: 10.1039/b604589h).
21. 21)
  - 20. Wang, M.: ‘Enhanced lithium storage performances of hierarchical hollow MoS2 nanoparticles assembled from nanosheets’, ACS Appl. Mater. Interf., 2013, 5, pp. 1003–1008 (doi: 10.1021/am3026954).
22. 22)
  - 28. Li, Y.D.: ‘Artificial lamellar mesostructures to WS2 nanotubes’, J. Am. Chem. Soc., 2002, 124, pp. 1411–1416 (doi: 10.1021/ja012055m).
23. 23)
  - 24. Wu, Z.Z.: ‘Synthesis of WS2 nanosheets by a novel mechanical activation method’, Mater. Lett., 2010, 64, pp. 856–858 (doi: 10.1016/j.matlet.2010.01.040).
24. 24)
  - 17. Greenberg, R.: ‘The effect of WS2 nanoparticles on friction reduction in various lubrication regimes’, Tribol. Lett., 2004, 17, pp. 179–186 (doi: 10.1023/B:TRIL.0000032443.95697.1d).
25. 25)
  - 44. Ho, W.K.: ‘Preparation and photocatalytic behavior of MoS2 and WS2 nanocluster sensitized TiO2’, Langmuir, 2004, 20, pp. 5865–5869 (doi: 10.1021/la049838g).
26. 26)
  - 45. Jing, D.W.: ‘WS2 sensitized mesoporous TiO2 for efficient hydrogen production from water under visible light irradiation’, Catal. Commun., 2007, 8, pp. 795–799 (doi: 10.1016/j.catcom.2006.09.009).
27. 27)
  - 5. Wang, Q.H.: ‘Electronics and optoelectronics of two-dimensional transition metal dichalcogenides’, Nat. Nanotechnol., 2012, 7, pp. 699–712 (doi: 10.1038/nnano.2012.193).
28. 28)
  - 18. Zhu, L.N.: ‘Microstructure and tribological properties of WS2/MoS2 multilayer films’, Appl. Surf. Sci., 2012, 258, pp. 1944–1948 (doi: 10.1016/j.apsusc.2011.06.148).
29. 29)
  - T.S. Ahmadi , Z.L. Wang , T.C. Green , A. Henglein , M.A. El-Sayed . Shape-controlled synthesis of colloidal platinum nanoparticles. Science , 1924 - 1925
30. 30)
  - 13. Dallavalle, M.: ‘Stability, dynamics, and lubrication of MoS2 platelets and nanotubes’, Langmuir, 2012, 28, pp. 7393–7400 (doi: 10.1021/la300871q).
31. 31)
  - 19. Feng, C.: ‘Synthesis of tungsten disulfide (WS2) nanoflakes for lithium ion battery application’, Electrochem. Commun., 2007, 9, pp. 119–122 (doi: 10.1016/j.elecom.2006.08.048).
32. 32)
  - 36. Cao, S.X.: ‘Hydrothermal synthesis of variety low dimensional WS2 nanostructures’, Mater. Lett., 2014, 129, pp. 205–208 (doi: 10.1016/j.matlet.2014.05.013).
33. 33)
  - 23. Lauritsen, J.V.: ‘Hydrodesulfurization reaction pathways on MoS2 nanoclusters revealed by scanning tunneling microscopy’, J. Catal., 2004, 224, pp. 94–106 (doi: 10.1016/j.jcat.2004.02.009).
34. 34)
  - 14. Rapoport, L.: ‘Friction and wear of fullerene-like WS2 under severe contact conditions: friction of ceramic materials’, Tribol. Lett., 2005, 19, pp. 143–149 (doi: 10.1007/s11249-005-5095-2).
35. 35)
  - 38. He, Q.Y.: ‘Hydrothermal synthesis of different 3D SnO2 nanostructures and their gas-sensing properties’, J. Mater. Sci., Mater. Electron., 2013, 24, pp. 2390–2397 (doi: 10.1007/s10854-013-1107-4).
36. 36)
  - 11. Chen, J.: ‘Synthesis of open-ended MoS2 nanotubes and the application as the catalyst of methanation’, Chem. Commun., 2002, 16, pp. 1722–1723 (doi: 10.1039/b205109e).
37. 37)
  - 22. Wu, Z.Z.: ‘WS2 nanosheets as a highly efficient electro catalyst for hydrogen evolution reaction’, Appl. Catal. B-Environ., 2012, 125, pp. 59–66 (doi: 10.1016/j.apcatb.2012.05.013).
38. 38)
  - 25. Gao, B.: ‘Template-free hydrothermal synthesis of α-molybdenum trioxide nanobelts and their photocatalytic activity for degradation of methylene blue’, Micro Nano Lett., 2013, 8, pp. 500–503 (doi: 10.1049/mnl.2013.0363).
39. 39)
  - Y.X. Zhou , Q. Zhang , J.Y. Gong , S.H. Yu . Surfactant-assisted hydrothermal synthesis and magnetic properties of urchin-like MnWO4 microspheres. J. Phys. Chem. C , 13383 - 13389
40. 40)
  - 2. Pol, V.G.: ‘WS2 breeds with carbon to create a wormlike nanostructure and assembly: reaction of W(CO)6 with S under autogenic pressure at elevated temperature under inert atmosphere’, J. Phys. Chem. C, 2007, 111, pp. 134–140 (doi: 10.1021/jp064417o).
41. 41)
  - 8. Kong, D.S.: ‘Synthesis of MoS2 and MoSe2 films with vertically aligned layers’, Nano Lett., 2013, 13, pp. 1341–1347 (doi: 10.1021/nl400258t).
42. 42)
  - 29. Sen, R.: ‘Encapsulated and hollow closed-cage structures of WS2 and MoS2 prepared by laser ablation at 450–1050°C’, Chem. Phys. Lett., 2001, 340, pp. 242–248 (doi: 10.1016/S0009-2614(01)00419-5).
43. 43)
  - 43. Guo, W.W.: ‘Gas-sensing property improvement of ZnO by hierarchical flower-like architectures’, Mater. Lett., 2011, 65, pp. 3384–3387 (doi: 10.1016/j.matlet.2011.07.059).
44. 44)
  - 26. Zhao, P.: ‘Preparation and characterization of molybdenum particles by reducing MoO3 nanofibers’, Synth. React. Inorg., Met.-Org., Nano-Met. Chem., 2008, 38, pp. 318–321.

Login

Not registered yet?

Share

Tools

Login to add to favourites

Key

Hydrothermal synthesis and controlled growth of tungsten disulphide nanostructures from one-dimension to three-dimensions

References

Related content