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In this work, the authors have successfully synthesised amorphous mesoporous magnesium silicate particles by the sol–gel technique combining with block copolymer P123 (EO20PO70EO20) as a template. Mesoporous magnesium silicate particles were characterised by X-ray diffraction, transmission electron microscopy, N2 adsorption–desorption technique, element mapping and energy-dispersive X-ray spectroscopy analysis. The results indicated that homogeneous amorphous mesoporous magnesium silicate particles have 298.4 m2/g of specific surface area and 5.5 nm of mesoporous channels. Using rhodamine B (RhoB) as a model dye, the adsorption capacity on mesoporous magnesium silicate particles can be estimated to 190 mg/g, and the regenerated particles also exhibited good adsorption performance. Therefore these mesoporous magnesium silicate particles have potential as adsorbents for the removal of dyes from water.
References
-
-
1)
-
R. Sanghi ,
B. Bhattacharya
.
Review on decolorisation of aqueous dye solutions by low cost adsorbents.
Coloration Technol.
,
256 -
269
-
2)
-
C.A.P. Almeida ,
N.A. Debacher ,
A.J. Downs ,
L. Cottet ,
C.A.D. Mello
.
Removal of methylene blue from colored effluents by adsorption on montmorillonite clay.
J. Colloid Interface Sci.
,
46 -
53
-
3)
-
F. Ciesielczyk ,
A. Krysztafkiewicz ,
T. Jesionowski
.
Magnesium silicates – adsorbents of organic compounds.
Appl. Surf. Sci.
,
8435 -
8442
-
4)
-
W. Xia ,
J. Chang
.
Preparation and the phase transformation behavior of amorphous mesoporous calcium silicate.
Micropor. Mesopor. Mater.
,
345 -
351
-
5)
-
J. Marto ,
P.S. Marcos ,
T. Trindade ,
J.A. Labrincha
.
Photocatalytic decolouration of Orange II by ZnO active layers screen-printed on ceramic tiles.
J. Hazard. Mater.
,
36 -
42
-
6)
-
P.S. Kumar ,
S. Ramalingam ,
K. Sathishkumar
.
Removal of methylene blue dye from aqueous solution by activated carbon prepared from cashew nut shell as a new low-cost adsorbent.
Korean J. Chem. Eng.
,
149 -
155
-
7)
-
R. Ryoo ,
S.H. Joo ,
S. Jun
.
Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation.
J. Phys. Chem. B
,
7743 -
7746
-
8)
-
A. Krysztafkiewicz ,
L.K. Lipska ,
F. Ciesielczyk ,
T. Jesionowski
.
Amorphous magnesium silicate — synthesis, physicochemical properties and surface morphology.
Adv. Powder Technol.
,
549 -
565
-
9)
-
M. Dogan ,
Y. Ozdemir ,
M. Alkan
.
Adsorption kinetics and mechanism of cationic methyl violet and methylene blue dyes onto sepiolite.
Dyes Pigm.
,
701 -
713
-
10)
-
G. Crini
.
Non-conventional low-cost adsorbents for dye removal: A review.
Bioresource Technol.
,
1061 -
1085
-
11)
-
J.L. Shi ,
Z.L. Hua ,
L.X. Zhang
.
Nanocomposites from ordered mesoporous materials.
J. Mater. Chem.
,
795 -
806
-
12)
-
A. Sayari ,
B. Han ,
Y. Yang
.
Simple synthesis route to monodispersed SBA-15 silica rods.
J. Am. Chem. Soc.
-
13)
-
W.Z. Tang ,
Z. Zhang ,
H. An ,
M.O. Quintana ,
D.F. Torres
.
TiO2/UV photodegradation of azo dyes in aqueous solutions.
Environ. Technol.
,
1 -
12
-
14)
-
Y. Özdemir ,
M. Doğan ,
M. Alkan
.
Adsorption of cationic dyes from aqueous solutions by scpiolite.
Micropor. Mesopor. Mater.
,
419 -
427
-
15)
-
R. Comparelli ,
E. Fanizza ,
M.L. Curri ,
P.D. Cozzoli ,
G. Mascolo ,
R. Passino ,
A. Agostiano
.
Photocatalytic degradation of azo dyes by organic-capped anatase TiO2 nanocrystals immobilized onto substrates.
Appl. Catal. B
,
81 -
91
-
16)
-
P. Canizares ,
F. Martinez ,
C. Jimenez ,
J. Lobato ,
M.A. Rodrigo
.
Coagulation and electrocoagulation of wastes polluted with dyes.
Environ. Sci. Technol.
,
6418 -
6424
-
17)
-
T.H. Kim ,
C. Park ,
J.M. Yang ,
S. Kim
.
Comparison of disperse and reactive dye removals by chemical coagulation and Fenton oxidation.
J. Hazard. Mater.
,
95 -
103
-
18)
-
C. Pelekani ,
V.L. Snoeyink
.
Competitive adsorption between atrazine and methylene blue on activated carbon: the importance of pore size distribution.
Carbon
,
1423 -
1436
-
19)
-
E. Razo-Flores ,
M. Luijten ,
B.A. Donlon ,
G. Lettinga ,
J.A. Field
.
Complete biodegradation of the azo dye azodisalicylate under anaerobic conditions.
Environ. Sci. Technol.
,
2098 -
2103
-
20)
-
F. Ferrero
.
Adsorption of methylene blue on magnesium silicate: kinetics, equilibria and comparison with other adsorbents.
J. Environ. Sci.
,
467 -
473
-
21)
-
Y. Wang ,
G. Wang ,
H. Wang ,
C. Liang ,
W. Cai ,
L. Zhang
.
Chemical-template synthesis of micro/nanoscale magnesium silicate hollow spheres for waste-water treatment.
Chem. Eur. J.
,
3497 -
3503
-
22)
-
S. Tanada ,
T. Kita ,
K. Boki ,
T. Tamura ,
Y. Murai
.
Mechanism of adsorption of methylene blue on magnesium silicate.
Chem. Pharm. Bull.
,
2503 -
2506
-
23)
-
S. Shin ,
J. Yang
.
Thiol containing polymer encapsulated magnetic nanoparticles as reusable and efficiently separable adsorbent for heavy metal ions.
Chem. Commun.
,
4230 -
4232
-
24)
-
X. Yan ,
C. Yu ,
X. Zhou ,
J. Tang ,
D. Zhao
.
Highly ordered mesoporous bioactive glasses with superior in vitro bone-forming bioactivities.
Angew. Chem. Int. Ed.
,
5980 -
5984
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