Comparative optical study of GaAs1−xNx/GaAs and BxGa1−xAs/GaAs epilayers

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Comparative optical study of GaAs1−xNx/GaAs and BxGa1−xAs/GaAs epilayers

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Optical studies of GaAs1−xNx/GaAs and BxGa1−xAs/GaAs epilayers grown by metal organic chemical vapour deposition (MOCVD), with various nitrogen (N) and boron (B) compositions, have been achieved by photoluminescence spectroscopy (PL) as a function of the excitation density and the sample temperature (10–300 K). The experiments have shown that the GaAsN PL band emission presents a more significant red shift than the BGaAs emission. For the GaAsN a reduction of 110 meV/1%N is shown, but for the BGaAs the PL band emission shifts to the low-energy side by up to 2.5%. A more significant blue shift of the PL bands with increasing the excitation density has been observed for GaAsN compared to BGaAs epilayer structures. The temperature dependence of the PL peak energy has shown S-shaped behaviour for both structures, but the localisation effects are more important in GaAsN than in BGaAs. Based on these experimental results, it is shown that B incorporation does not cause large modification of the band structure in BxGa1−xAs alloys compared to pure GaAsN structures.

Inspec keywords: gallium arsenide; energy gap; gallium compounds; semiconductor growth; photoluminescence; semiconductor doping; boron; nitrogen; red shift; MOCVD; semiconductor epitaxial layers; III-V semiconductors

Other keywords: MOCVD; GaAs1-xNx-GaAs; blue shift; band structure; photoluminescence spectroscopy; 10 to 300 K; localisation effects; GaAs1-xNx/GaAs epilayers; BxGa1-xAs-GaAs; BxGa1-xAs/GaAs epilayers; metal organic chemical vapour deposition; red shift; excitation density

Subjects: Semiconductor doping; Chemical vapour deposition; Optical properties of II-VI and III-V semiconductors (thin films, low-dimensional and nanoscale structures); Doping and implantation of impurities; II-VI and III-V semiconductors; Photoluminescence in II-VI and III-V semiconductors; Chemical vapour deposition

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