A review of recombination in silicon thin-film solar cells studied by means of electrically detected magnetic resonance (EDMR) is presented. It is shown that the EDMR results in μc-Si:H p-i-n solar cells can be described by a simple diffusion model that was developed for crystalline silicon p-n junctions assuming that recombination is dominated by dangling bonds in the space charge region. The results are compared to a-Si:H p-i-n cells and discussed in a recombination model involving the excited states of charged dangling bonds.
References
-
-
1)
-
S.M. Sze
.
(1981)
Physics of semiconductor devices.
-
2)
-
K. Lips ,
K. Kanschat ,
W. Fuhs
.
Defects and recombination in microcrystalline silicon.
Sol. Energy Mater. Sol. Cells
,
513 -
541
-
3)
-
K. Lips ,
M. Blick ,
W. Fuhs ,
C. Lerner
.
Degradation of a-Si:H p-i-n solar cells studied by EDMR.
J. Non-Cryst. Solids
,
697 -
700
-
4)
-
A.L. Baia Neto ,
A. Lambertz ,
R. Carius ,
F. Finger
.
Relationships between structure, spin density and electronic transport in solar-grade microcrystalline silicon films.
J. Non-Cryst. Solids
,
274 -
279
-
5)
-
C. Boehme ,
K. Lips
.
Light-intensity and temperature dependence of trap dangling-bond recombination in hydrogenated microcrystalline silicon.
Mat. Res. Soc. Symp. Proc.
-
6)
-
P. Kanschat ,
K. Lips ,
R. Brüggemann ,
A. Hierzenberger ,
I. Sieber ,
W. Fuhs
.
Paramagnetic defects in undoped microcrystalline silicon deposited by the hot-wire technique.
Mat. Res. Soc. Symp. Proc.
,
793 -
798
-
7)
-
M.F. Chisholm ,
R. Buczko ,
M. Mostoller ,
T. Taplan ,
A. Maiti ,
S.T. Pantelides ,
S.J. Pennycook
.
Atomic structure and properties of extended defects in silicon.
Diffus. Defect Data B, Solid State Phenom.
,
3 -
14
-
8)
-
Boehme, C.: `Dynamics of spin-dependent charge carrier recombination', 2003, PhD, Cuvillier Verlag Göttingen, Germany, Marburg, Germany.
-
9)
-
K. Lips ,
C. Boehme
.
Recombination echoes in disordered silicon.
J. Mater. Sci. Mater. Electron.
-
10)
-
H. Keppner ,
J. Meier ,
P. Torres ,
D. Fischer ,
A. Shah
.
Microcrystalline silicon and micromorph tandem solar cells.
Appl. Phys. A, Mater. Sci. Process.
,
169 -
177
-
11)
-
R. Maxwell ,
A. Honig
.
Neutral-impurity scattering experiments in silicon with highly spin-polarized electrons.
Phys. Rev. Lett.
,
188 -
190
-
12)
-
K. Lips ,
W. Fuhs
.
Transport and recombination in amorphous p-i-n-type solar cells studied by electrically detected magnetic resonance.
J. Appl. Phys.
,
3993 -
3999
-
13)
-
F.C. Rong ,
W.R. Buchwald ,
E.H. Poindexter ,
W.L. Warren ,
D.J. Keeble
.
Spin-dependent Shockley-Read recombination of electrons and holes in indirect-band-gap semiconductor p-n junction diodes.
Solid-State Electron.
,
835 -
841
-
14)
-
D. Xiong ,
Z.J. Miller
.
Detailed investigation of a nonradiative recombination center in Si by EDMR.
J. Appl. Phys.
-
15)
-
Y. Nasuno ,
M. Kondo ,
A. Matsuda
.
Passivation of oxygen-related donors in microcrystalline silicon by low temperature deposition.
Appl. Phys. Lett.
,
2330 -
2332
-
16)
-
P. Christmann ,
C. Wetzel ,
B.K. Meyer ,
A. Asenov ,
A. Endros
.
Spin dependent recombination in Pt-doped silicon p-n junctions.
Appl. Phys. Lett.
,
1857 -
1859
-
17)
-
K. Lips ,
R. Müller ,
P. Kanschat ,
F. Finger ,
W. Fuhs
.
Spin-dependent processes in thin film Si solar cells.
Mat. Res. Soc. Symp. Proc.
,
A18.2.1 -
A18.2.12
-
18)
-
I. Solomon
.
Spin-dependent recombination in a silicon pn junctions.
Solid State Commun.
,
215 -
217
-
19)
-
O. Vetterl ,
F. Finger ,
C. Carius ,
P. Hapke ,
L. Houben ,
O. Kluth ,
A. Lambertz ,
A. Mück ,
B. Rech ,
H. Wagner
.
Intrinsic microcrystalline silicon: a new material for photovoltaics.
Sol. Energy Mater. Sol. Cells
-
20)
-
K. Kondo ,
A. Matsuda
.
Low temperature growth of microcrystalline silicon and its application to solar cells.
Thin Solid Films
,
1 -
6
-
21)
-
P. Kanschat ,
K. Lips ,
W. Fuhs
.
Identification of non-radiative recombination paths in microcrystalline silicon (μc-Si:H).
J. Non-Cryst. Solids
,
524 -
528
-
22)
-
M. Block
.
J. Non-Cryst. Solids.
J. Non-Cryst. Solids
,
701 -
705
-
23)
-
Lips, K., Fuhs, W., Finger, F.: `Recombination currents in microcrystalline silicon solar cells studied by electrically detected magnetic resonance', Proc. 29th IEEE Photovoltaic Specialists Conf., 2002, p. 1166–1169.
-
24)
-
J.H. Zhou ,
S. Yamasaki ,
J. Isoya ,
K. Ikuta ,
M. Kondo ,
A. Matsuda ,
K. Tanaka
.
Pulsed ESR study of the conduction …..
Mat. Res. Soc. Symp. Proc.
,
821 -
826
-
25)
-
D.J. Lepine
.
Spin-dependent recombination on silicon surface.
Phys. Rev. B
,
436 -
441
-
26)
-
Lips, K.: `Spinabhängkeit von Transport und Rekombination in Filmen und Solarzellen aus amorphen Silizum', 1994, PhD, Philipps-Universität, Marburg, Germany, Cuvillier Verlag Göttingen, Germany.
-
27)
-
F. Rong ,
E.H. Poindexter ,
M. Harmatz ,
W.R. Buchwald ,
G.J. Geradi
.
EDMR in pn junction diodes.
Solid State Commun.
-
28)
-
K. Lips ,
J. Platen ,
S. Brehme ,
S. Gall ,
I. Sieber ,
L. Elstner ,
W. Fuhs
.
Preparation and characterization of microcrystalline and epitactially grown emitter layers for silicon solar cells.
Mat. Res. Soc. Symp. Proc.
-
29)
-
K. Lips
.
Spin-dependent recombination effects in a-Si:H pin solar cell devices: a new characterization technique.
Mat. Res. Soc. Symp. Proc.
,
455 -
466
-
30)
-
R. Müller ,
P. Kanschat ,
S. von Aichberger ,
K. Lips ,
W. Fuhs
.
Identification of transport and recombination paths in homo- and heterojunction silicon solar cells by electrically detected magnetic resonance.
J. Non-Cryst. Solids
-
31)
-
J.H. Werner ,
R. Dassow ,
T.J. Rinke ,
J.R. Köhler ,
R.B. Bergmann
.
From polycrystalline to single crystalline silicon on glass.
Thin Solid Films
,
95 -
100
-
32)
-
K. Yamamoto ,
T. Suzuki ,
M. Yoshimi ,
A. Nakajima
.
Optical confinement effect for below 5 μm thin film poly-Si solar cell on glass substrate.
Jpn. J. Appl. Phys., 2, Lett.
,
L569 -
L572
http://iet.metastore.ingenta.com/content/journals/10.1049/ip-cds_20030578
Related content
content/journals/10.1049/ip-cds_20030578
pub_keyword,iet_inspecKeyword,pub_concept
6
6