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Multiple monolayer adsorption—a new technique for the production of noncentrosymmetric films

Multiple monolayer adsorption—a new technique for the production of noncentrosymmetric films

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© The Institution of Electrical Engineers
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A new technique is described, whereby a multilayer film is built-up monolayer by monolayer by adsorption of suitable amphiphilic fluorocarbons from alternately hexadecane then water. The capacitance-thickness measurements indicate good, uniform monolayer coverage.

Inspec keywords: monolayers; adsorbed layers; thin films; coating techniques

Other keywords: capacitance-thickness measurements; hexadecane; pin-hole-free type; uniform monolayer coverage; amphiphilic fluorocarbons; ultrathin films; thin film deposition; >1 micron; multilayer film; noncentrosymmetric films; coating techniques; water

Subjects: Thin film growth and epitaxy; Solid-fluid interface processes; Deposition from liquid phases (melts and solutions); Thin film growth, structure, and epitaxy

References

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      • L. Netzer , R. Iscovici , S. Sagiv . Adsorbed monolayers versus Langmuir-Blodgett monolayers—why and how?. Thin Solid Films , 235 - 242
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      • W.A. Barlow . (1980) , Langmuir-Blodgett films.
    3. 3)
      • R.H. Tredgold , Z.I. El-badawy . Increase of Schottky barrier height at GaAs surfaces by carboxylic acid monolayers and multilayers. J. Phys. D , 103 - 109
    4. 4)
      • K.B. Blodgett . Films built up by depositing successive monomolecular layers on a solid surface. J. Am. Chem. Soc. , 1007 - 1022
    5. 5)
      • R.H. Tredgold , G.W. Smith . Schottky photodiodes incorporating monolayers formed by adsorption and by the Langmuir-Blodgelt technique. IEE Proc. I, Solid-State & Electron Dev. , 4 , 137 - 140
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