Improving the gas sensing response of polyaniline via a porous carbon nanotube-based template
- Author(s): Wei Li 1 ; Panpan Guan 1 ; Aili Wei 1 ; Huaiping Zhang 1 ; Hui Zhai 2
-
-
View affiliations
-
Affiliations:
1:
Department of Material Science, Taiyuan University of Technology, Taiyuan 030024, People's Republic of China;
2: Shenyang Products Quality Supervision and Inspection Research Institute, Shenyang 110023, People's Republic of China
-
Affiliations:
1:
Department of Material Science, Taiyuan University of Technology, Taiyuan 030024, People's Republic of China;
- Source:
Volume 10, Issue 4,
April 2015,
p.
206 – 208
DOI: 10.1049/mnl.2014.0638 , Online ISSN 1750-0443
Tin metal was coated onto single-walled carbon nanotubes by sputtering and then thermally oxidised to form a stable tin oxide/single-walled carbon nanotubes porous template on glass substrate. Polyaniline (PANI) was coated onto this template through oxidative polymerisation. The nanocomposite was characterised by scanning electron microscopy, infrared spectra and Raman spectra. The sensor response of the nanocomposite to an aromatic organic compound (AOC) was investigated in the comparison with pure PANI. The results show that, upon exposure to the AOC, the conductivity of the sensor increases and the response of the nanocomposite is much higher than that of pure PANI.
Inspec keywords: sputter deposition; nanocomposites; gas sensors; infrared spectra; oxidation; nanosensors; tin compounds; polymerisation; wide band gap semiconductors; scanning electron microscopy; polymers; Raman spectra; nanofabrication; electrical conductivity; nanoporous materials
Other keywords: conductivity; stable tin oxide/single-walled carbon nanotubes porous template; nanocomposite; polyaniline gas sensing response; oxidative polymerisation; thermal oxidation; scanning electron microscopy; aromatic organic compound; SiO2; glass substrate; sputtering; infrared spectrum; Raman spectrum; SEM; C−SnO2
Subjects: Micromechanical and nanomechanical devices and systems; Fabrication of MEMS and NEMS devices; Microsensors and nanosensors; Chemical sensors; Chemical sensors; Sputter deposition
References
-
-
1)
-
4. Chiou, N.R., Epstein, A.J.: ‘Polyaniline nanofibers prepared by dilute polymerization’, Adv. Mater., 2005, 17, pp. 1679–1683 (doi: 10.1002/adma.200401000).
-
-
2)
-
24. Virji, S., Huang, J., Kaner, B.R., Weiller, B.H.: ‘Polyaniline nanofiber gas sensors: examination of response mechanisms’, Nano Lett., 2004, 4, pp. 491–496 (doi: 10.1021/nl035122e).
-
-
3)
-
8. Wu, Z., Chen, X., Zhu, S., et al: ‘Enhanced sensitivity of ammonia sensor using graphene polyaniline nanocomposite’, Sen. Actuators B, 2013, 178, pp. 485–493 (doi: 10.1016/j.snb.2013.01.014).
-
-
4)
-
13. Nguyen, D.H., Nguyen, V.Q., Song, H., Kang, Y., Cho, Y., Kim, D.: ‘Tin oxidenanotube structures synthesized on a template of single-walled carbon nanotubes’, J. Crystal Growth, 2009, 311, pp. 657–661 (doi: 10.1016/j.jcrysgro.2008.09.076).
-
-
5)
-
17. Sutar, D.S., Padma, N., Aswal, D.K., Deshpande, D.H., Gupta, S.K., Yakhmi, J.V.: ‘Preparation of nanofibrous polyaniline films and their application as ammonia gas sensor’, Sens. Actuators B, 2007, 128, pp. 286–292 (doi: 10.1016/j.snb.2007.06.015).
-
-
6)
-
11. Wang, P.C., Dan, Y., Liu, L.H.: ‘Effect of thermal treatment on conductometric response of hydrogen gas sensors integrated with HCl-doped polyaniline nanofibers’, Mater. Chem. Phys., 2014, 144, pp. 155–161 (doi: 10.1016/j.matchemphys.2013.12.035).
-
-
7)
-
10. Nasirian, S., Moghaddam, H.M.: ‘Hydrogen gas sensor based on polyaniline/anatase titania nanocomposite’, Int. J. Hydrog. Energy, 2014, 39, pp. 630–642 (doi: 10.1016/j.ijhydene.2013.09.152).
-
-
8)
-
26. Li, Z.F., Blum, F.D., Bertino, M.F., Kim, C.S.: ‘Amplified response and enhanced selectivity of metal-PANI fiber composite based vapor sensors’, Sens. Actuators B, 2012, 161, pp. 390–395 (doi: 10.1016/j.snb.2011.10.049).
-
-
9)
-
19. Li, W., Kim, D.: ‘Polyaniline/multiwall carbon nanotube nanocomposite for detecting aromatic hydrocarbon vapors’, J. Mater. Sci., 2011, 46, pp. 1857–1861 (doi: 10.1007/s10853-010-5013-3).
-
-
10)
-
1. Li, W., Nguyen, D.H., Cho, Y., Kim, D., Kim, J.: ‘Nanofibers of conducting polyaniline for aromatic organic compound sensor’, Sens. Actuators B, 2009, 143, pp. 132–138 (doi: 10.1016/j.snb.2009.09.006).
-
-
11)
-
21. Roh, J.G., Hwang, H.R., Yu, J.B., Lim, J.O., Huh, J.S.: ‘Oxidant effects on polypyrrole and polyaniline sensor for several volatile organic gases’, J. Macromolecular Sci. A, 2002, 39, pp. 1095–1105 (doi: 10.1081/MA-120014837).
-
-
12)
-
18. Louarn, G., Lapkowski, M., Quillard, S., Pron, A., Buisson, J.P., Lefrant, S.: ‘Vibrational properties of polyaniline-isotope effects’, J. Phys. Chem., 1996, 100, pp. 6998–7006 (doi: 10.1021/jp953387e).
-
-
13)
-
22. Kim, J.S., Sohn, S.O., Huh, J.S.: ‘Fabrication and sensing behavior of PVF2 coated-polyaniline sensor for volatile organic compounds’, Sens. Actuators B, 2005, 108, pp. 409–413 (doi: 10.1016/j.snb.2004.11.072).
-
-
14)
-
25. Li, Z.F., Blum, F.D., Bertino, M.F., Kim, C.S.: ‘Understanding the response of nanostructured polyaniline gas sensor’, Sens. Actuators. B, 2013, 183, pp. 419–427 (doi: 10.1016/j.snb.2013.03.125).
-
-
15)
-
16. Li, W., Wei, A.L., Zhang, H.P., Kim, D.: ‘One-dimensional organic-inorganic nanocomposite synthesized with single-walled carbon nanotube templates’, Materials, 2014, 7, pp. 5858–5865 (doi: 10.3390/ma7085858).
-
-
16)
-
23. Potyrailo, R.A., Surman, C., Burns, A.: ‘Materials and transducers toward selective gas sensing’, Chem. Rev., 2011, 111, pp. 7315–7354 (doi: 10.1021/cr2000477).
-
-
17)
-
5. Oueiny, C., Berlioz, S., Perrin, F.X.: ‘Carbon nanotube–polyaniline composites’, Prog. Poly. Sci., 2014, 39, pp. 707–748 (doi: 10.1016/j.progpolymsci.2013.08.009).
-
-
18)
-
15. Nguyen, D.H., Nguyen, V.H., Kim, D.: ‘Nanowire structured SnOx–SWNT composites: high performance sensor for NOx detection’, Sens. Actuators B, 2009, 142, pp. 253–259 (doi: 10.1016/j.snb.2009.07.053).
-
-
19)
-
3. Huang, J., Kaner, R.B.: ‘Nanofiber formation in the chemical polymerization of aniline: a mechanistic study’, Angew. Chem. Int. Ed., 2004, 43, pp. 5817–5821 (doi: 10.1002/anie.200460616).
-
-
20)
-
2. Jain, M., Annapoorni, S.: ‘Raman study of polyaniline nanofibers prepared by interfacial polymerization’, Synth. Metals, 2010, 160, pp. 1727–1732 (doi: 10.1016/j.synthmet.2010.06.008).
-
-
21)
-
6. Girschikofsky, M., Rosenberger, M., Belle, S., Brutschy, M., Waldvogel, S.R., Hellmann, R.: ‘Optical planar Bragg grafting sensor for real time detection of benzene, toluene and xylene in solvent vapour’, Sens. Actuators B, 2012, 171–172, pp. 338–342 (doi: 10.1016/j.snb.2012.04.046).
-
-
22)
-
7. Talwar, V., Singh, O., Singh, R.C.: ‘ZnO assisted polyaniline nanofibers and its application as ammonia gas sensor’, Sens. Actuators B, 2014, 191, pp. 276–282 (doi: 10.1016/j.snb.2013.09.106).
-
-
23)
-
20. Lide, D.R.: ‘Handbook of chemistry and physics’ (CRC Press, Boca Raton, FL, USA, 2005, 85th edn).
-
-
24)
-
9. Sharma, A.l., Kumar, K., Deep, A.: ‘Nanostructured polyaniline films on silicon for sensitive sensing of ammonia’, Sens. Actuators A, 2013, 198, pp. 107–112 (doi: 10.1016/j.sna.2013.04.026).
-
-
25)
-
12. Li, W., Jang, D.M., An, S.Y., Kim, D., Hong, S.K., Kim, H.: ‘Polyaniline-nanocomposite: high performance hydrogen sensor from new principle’, Sens. Actuators B, 2011, 160, pp. 1020–1025 (doi: 10.1016/j.snb.2011.09.020).
-
-
1)