Effect of aluminium doping amount on the electrochemical properties of ZnO nanoparticles as anode for lithium ion batteries

Lifeng Zhang; Jinzhen Zhang; Yi Liu; Shouwu Guo

Effect of aluminium doping amount on the electrochemical properties of ZnO nanoparticles as anode for lithium ion batteries

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Author(s): Lifeng Zhang ¹ ; Jinzhen Zhang ¹ ; Yi Liu ¹ ; Shouwu Guo ¹
- Affiliations: 1: College of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi'an, Shaanxi 710021, People's Republic of China
Source: Volume 10, Issue 4, April 2015, p. 217 – 219
DOI: 10.1049/mnl.2014.0631 , Online ISSN 1750-0443

Received 18/11/2014, Accepted 05/02/2015, Revised 15/01/2015, Published 24/03/2015

Aluminium (Al)-doped ZnO nanoparticles (NPs) have been synthesised by a simple solvothermal method at low temperature. The electrochemical properties of the obtained products as anode for lithium ion batteries were examined through galvanostatic discharge–charge, cyclic voltammetry and electrochemical impedance spectroscopy measurements. The results show that the reversible capacities of Al-doped ZnO NPs are higher than the capacities of pure ZnO synthesised under the same experimental conditions. ZnO NPs doped with 2% (molar ratio) of Al show the best electrochemical properties with reversible specific capacities of 418 mA·h·g⁻¹ at a current density of 50 mA·g⁻¹. The enhanced electrochemical performance of this material could be attributed to the improved electronic conductivity because of the doping of Al³⁺ at an appropriate concentration.

References

1. 1)
  - 11. Li, H., Huang, X., Chen, L.: ‘Anodes based on oxide materials for lithium rechargeable batteries’, Solid State Ion., 1999, 123, pp. 189–197 (doi: 10.1016/S0167-2738(99)00081-8).
2. 2)
  - 19. Che, G., Lakshmi, B.B., Fisher, E.R., Martin, C.R.: ‘Carbon nanotubule membranes for electrochemical energy storage and production’, Nature, 1998, 393, pp. 346–348 (doi: 10.1038/30694).
3. 3)
  - 18. Brousse, T., Derives, D., Pasquereau, L., Lee, S.M., Herterich, U., Schleich, D.M.: ‘Metal oxide anodes for Li-ion batteries’, Ionics, 1997, 3, pp. 332–337 (doi: 10.1007/BF02375707).
4. 4)
  - 1. Tan, C.L., Zhou, H.J., Li, W.S., Hou, X.H., Lu, D.S.: ‘Performance improvement of LiMn2O4 as cathode material for lithium ion battery with bismuth modification’, J. Power Sources, 2008, 184, pp. 408–413 (doi: 10.1016/j.jpowsour.2008.04.019).
5. 5)
  - 13. Huang, X.H., Xia, X.H., Yuan, Y.F., Zhou, F.: ‘Porous ZnO nanosheets grown on copper substrates as anodes for lithium ion batteries’, Electrochim. Acta, 2011, 56, pp. 4960–4965 (doi: 10.1016/j.electacta.2011.03.129).
6. 6)
  - 16. Wang, R.P., Sleight, A.W., Cleary, D.: ‘High conductivity in gallium-doped zinc oxide powders’, Chem. Mater., 1996, 8, pp. 433–439 (doi: 10.1021/cm950372k).
7. 7)
  - 6. Taberna, L., Mitra, S., Poizot, P., Simon, P., Tarascon, J.M.: ‘High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications’, Nature Mater., 2006, 5, pp. 567–573 (doi: 10.1038/nmat1672).
8. 8)
  - 3. Bai, Z.A., Zhang, Y.W., Fan, N., Guo, C.L., Tang, B.: ‘One-step synthesis of ZnO@C nanospheres and their enhanced performance for lithium-ion batteries’, Mater. Lett., 2014, 119, pp. 16–19 (doi: 10.1016/j.matlet.2013.12.060).
9. 9)
  - J.M. Tarascon , M. Armard . Issues and challenges facing rechargeable lithium batteries. Nature , 359 - 367
10. 10)
  - 9. Kadam, P., Agashe, C., Mahamuni, S.: ‘Al-doped ZnO nanocrystals’, J. Appl. Phys., 2008, 104, pp. 103501–103504 (doi: 10.1063/1.3020527).
11. 11)
  - 12. Huang, X.H., Guo, R.Q., Wu, J.B., Zhang, P.: ‘Mesoporous ZnO nanosheets for lithium ion batteries’, Mater. Lett., 2014, 122, pp. 82–85 (doi: 10.1016/j.matlet.2014.02.012).
12. 12)
  - 8. Belliard, F., Connor, P.A., Irvine, J.T.S.: ‘Doped tin oxides as potential lithium ion battery negative electrodes’, Ionics, 1999, 5, pp. 450–454 (doi: 10.1007/BF02376012).
13. 13)
  - D.J. Norris , A.L. Efros , S.C. Erwin . Doped nanocrystals. Science , 1776 - 1779
14. 14)
  - 17. Taylor, M.P., Readey, D.W., Hest, M.V., Teplin, C.W.: ‘The remarkable thermal stability of amorphous In-Zn-O transparent conductors’, Adv. Funct. Mater., 2008, 18, pp. 3169–3178 (doi: 10.1002/adfm.200700604).
15. 15)
  - 2. Zhang, X.F., Liu, J., Yu, H.Y., Yang, G.L., Wang, J.W., Yu, Z.J.: ‘Enhanced electrochemical performances of LiNi0.5Mn1.5O4 spinel via ethylene glycol-assisted synthesis’, Electrochim. Acta, 2010, 55, pp. 2414–2417 (doi: 10.1016/j.electacta.2009.12.001).
16. 16)
  - P. Poizot , S. Laruelle , S. Grugeon , L. Dupont , J.-M. Tarascon . Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature , 496 - 499
17. 17)
  - 15. Lin, D., Wu, H., Pan, W.: ‘Photoswitches and memories assembled by electrospinning aluminum-doped zinc oxide single nanowires’, Adv. Mater., 2007, 19, pp. 3968–3972 (doi: 10.1002/adma.200602802).
18. 18)
  - 10. Belliard, F., Connor, P.A., Irvine, J.T.S.: ‘Novel tin oxide-based anodes for Li-ion batteries’, Solid State Ion., 2000, 135, pp. 163–167 (doi: 10.1016/S0167-2738(00)00296-4).
19. 19)
  - 20. Belliard, F., Irvine, J.T.S.: ‘Electrochemical performance of ball-milled ZnO-SnO2 systems as anodes in lithium ion battery’, J. Power Sources, 2001, 97, pp. 219–222 (doi: 10.1016/S0378-7753(01)00544-4).
20. 20)
  - 7. Li, H., Balaya, P., Maier, J.: ‘Li-storage via heterogeneous reaction in selected binary metal fluorides and oxides’, J. Electrochem. Soc., 2004, 151, pp. A1878–A1885 (doi: 10.1149/1.1801451).

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Effect of aluminium doping amount on the electrochemical properties of ZnO nanoparticles as anode for lithium ion batteries

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