© The Institution of Engineering and Technology
A novel method has been developed to prepare efficient electrocatalysts for methanol oxidation using graphene oxide (GO) as the support, and the deposited Pt–Ru particles on the sheets of GO are very thin nanoplatelets. The method mainly includes the following steps: Pb2+ adsorption on the sheets of GO, Pb2+ electrochemical reduction and galvanic displacement of Pb0 by Pt2+ and Ru3+. The prepared catalyst displays a large electrochemically active surface area and its mass electrocatalytic activity towards methanol oxidation reaction is about 15 times higher than that of commercial catalysts. The presented results demonstrate that this developed method could be viable for solving the problem of low electrocatalytic activity in direct methanol fuel cell anodes.
References
-
-
1)
-
20. Rauhe, B.R.Jr., McLarnon, F.R., Cairns, E.J.: ‘Direct anodic oxidation of methanol on supported platinum/ruthenium catalyst in aqueous cesium carbonate’, J. Electrochem. Soc., 1995, 142, pp. 1073–1084 (doi: 10.1149/1.2044547).
-
2)
-
11. Salgado, J.R.C., Paganin, V.A., Gonzalez, E.R., et al: ‘Characterization and performance evaluation of Pt–Ru electrocatalysts supported on different carbon materials for direct methanol fuel cells’, Int. J. Hydrog. Energy, 2013, 38, pp. 910–920 (doi: 10.1016/j.ijhydene.2012.10.079).
-
3)
-
3. Sharma, S., Pollet, B.: ‘Support materials for PEMFC and DMFC electrocatalysts – a review’, J. Power Sources, 2012, 208, pp. 96–119 (doi: 10.1016/j.jpowsour.2012.02.011).
-
4)
-
28. Bambagioni, V., Bianchini, C., Marchionni, A., et al: ‘Pd and Pt–Ru anode electrocatalysts supported on multi-walled carbon nanotubes and their use in passive and active direct alcohol fuel cells with an anion-exchange membrane (alcohol = methanol, ethanol, glycerol)’, J. Power Sources, 2009, 190, (2), pp. 241–251 (doi: 10.1016/j.jpowsour.2009.01.044).
-
5)
-
27. Qian, Y., Wen, W., Adcock, P.A., et al: ‘PtM/C catalyst prepared using reverse micelle method for oxygen reduction reaction in PEM fuel cells’, J. Phys. Chem. C, 2008, 112, (4), pp. 1146–1157 (doi: 10.1021/jp074929i).
-
6)
-
17. Dong, L., Gary, R.R.S., Li, Z., Craig, M.M., Hou, S.F.: ‘Graphene-supported platinum and platinum–ruthenium nanoparticles with high electrocatalytic activity for methanol and ethanol oxidation’, Carbon, 2010, 48, pp. 781–787 (doi: 10.1016/j.carbon.2009.10.027).
-
7)
-
10. Zhou, Y.G., Chen, J.J., Wang, F.B., Sheng, Z.H., Xia, X.H.: ‘A facile approach to the synthesis of highly electroactive Pt nanoparticles on graphene as an anode catalyst for direct methanol fuel cells’, Chem. Commun., 2010, 46, pp. 5951–5953 (doi: 10.1039/c0cc00394h).
-
8)
-
14. Sieben, J.M., Duarte, M.M.E., Mayer, C.E.: ‘Electro-oxidation of methanol on Pt-Ru nanostructured catalysts electrodeposited onto electroactivated carbon fiber materials’, Chem. Catal. Chem., 2010, 2, pp. 182–189.
-
9)
-
26. Yu, J.-S., Kang, S., Yoon, S.B., Chai, G.: ‘Fabrication of ordered uniform porous carbon networks and their application to a catalyst supporter’, J. Am. Chem. Soc., 2002, 124, (32), pp. 9382–9383 (doi: 10.1021/ja0203972).
-
10)
-
E. Yoo ,
T. Okata ,
T. Akita ,
M. Kohyama ,
J. Nakamura ,
I. Honma
.
Enhanced electrocatalytic activity of Pt subnanoclusters on graphene nanosheets surface.
Nano Lett.
,
2255 -
2259
-
11)
-
9. Nilekar, A.U., Sasaki, K., Farberow, C., Adzic, R., Mavrikakis, M.: ‘Mixed-metal Pt monolayer electrocatalysts with improved CO tolerance’, J. Am. Chem. Soc., 2011, 133, pp. 18574–18576 (doi: 10.1021/ja2072675).
-
12)
-
4. Qiu, J., Wang, G., Liang, R., Xia, X., Yu, H.: ‘Controllable deposition of platinum nanoparticles on graphene as an electrocatalyst for direct methanol fuel cells’, J. Phys. Chem. C, 2011, 115, pp. 15639–15645 (doi: 10.1021/jp200580u).
-
13)
-
30. Chai, G.S., Fang, B., Yu, J.-S.: ‘γ-ray irradiation as highly efficient approach for synthesis of supported high Pt loading cathode catalyst for application in direct methanol fuel cell’, Electrochem. Commun., 2008, 10, (11), pp. 1801–1804 (doi: 10.1016/j.elecom.2008.09.021).
-
14)
-
A.K. Geim ,
K.S. Nososelov
.
The rise of graphene.
Nature Mater.
,
183 -
191
-
15)
-
2. Xin, Y.C., Liu, J.G., Zhou, Y., et al: ‘Preparation and characterization of Pt supported on graphene with enhanced electrocatalytic activity in fuel cell’, J. Power Sources, 2011, 196, pp. 1012–1018 (doi: 10.1016/j.jpowsour.2010.08.051).
-
16)
-
Y.M. Li ,
L.H. Tang ,
J.H. Li
.
Preparation and electrochemical performance for methanol oxidation of Pt/graphene nanocomposites.
Electrochem. Commun.
,
846 -
849
-
17)
-
4. Hamnett, A.: ‘Mechanism and electrocatalysis in the direct methanol fuel cell’, Catal. Today, 1997, 38, pp. 445–457 (doi: 10.1016/S0920-5861(97)00054-0).
-
18)
-
12. Chetty, R., Kundu, S., Xia, W., et al: ‘PtRu nanoparticles supported on nitrogen-doped multiwalled carbon nanotubes as catalyst for methanol electrooxidation’, Electrochim. Acta, 2009, 54, pp. 4208–4215 (doi: 10.1016/j.electacta.2009.02.073).
-
19)
-
24. Guo, S., Dong, S., Wang, E.: ‘Three-dimensional Pt-on-Pd bimetallic nanodendrites supported on graphene nanosheet: facile synthesis and used as an advanced nanoelectrocatalyst for methanol oxidation’, ACS Nano, 2009, 4, (1), pp. 547–555 (doi: 10.1021/nn9014483).
-
20)
-
18. Ando, Y., Sasaki, K., Adzic, R.: ‘Electrocatalysts for methanol oxidation with ultra low content of Pt and Ru’, Electrochem. Commun., 2009, 11, pp. 1135–1138 (doi: 10.1016/j.elecom.2009.03.031).
-
21)
-
W.S. Hummers ,
R.E. Offeman
.
Preparation of graphite oxide.
J. Am. Chem. Soc.
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